She takes on the role of a sex starved dentist in her new film and at the photo-call for the premiere Jennifer Aniston opted for something a little racy in keeping with her character.
The 42-year-old actress - who is in London for the premiere of Horrible Bosses - stepped out in a simple yet seductive black leather dress.
The star, who is best known for playing Rachel Green in Friends, accessorised in a pair of strappy sandals and a two bracelets on her left wrist.
Jennifer showed off an inking, seen on the inside of her right foot, which is a tribute to her dog Norman, who passed away in May.
Jennifer joined co-stars Jason Sudeikis, Charlie Day, Jason Bateman and Kevin Spacey who star in the comedy.
The cast will be attending the premiere for the film at BFI Southbank later this evening.
Speaking about her role as Dr Julia Harris, who blackmails her male assistant, she told The Sun: ‘It was great fun and very liberating to throw myself into this character.’
‘You feel totally uninhibited and get to explore your weirdest and kinkiest psychological quirks and just exaggerate all the kinds of flirtatious ideas and fantasies you've ever had.
‘You get to enjoy being fearless when you play a character that is so brazen and domineering.’
Earlier this month Jennifer was inducted into the Hollywood Walk Of Fame and her new boyfriend Justin Theroux was front row to support his leading lady.
Although she kept him hidden while she walked the red carpet at last Thursday's Horrible Bosses premiere in Los Angeles, Justin was pride of place at the drinks later that night.
After meeting up inside the premiere, the couple spent an hour and a half at the after-party before heading to the Chateau Marmont to meet friends, including her Courteney Cox.
An onlooker told People magazine: 'They were super cute. He had his arm around her and kissed her on her cheek. They were whispering in each other's ears.'
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